Wait a moment for the iPod to appear on the desktop. If it doesn't, unplug and reconnect the charger cable; sometimes it takes a couple of tries.
Double-click the iPod icon on the desktop when it appears. The iPod opens and reveals its files.
When you connect your iPod to your Mac desktop or laptop computer, the iPod's name and icon appear on computer's desktop. Most people don't have occasion to open the iPod from their desktop because songs transferred from iTunes generally have short, random titles, making them hard to recognize. However, if you're using your iPod in disc mode -- basically as a portable hard drive -- opening it from your Mac desktop is the fastest way to access the files.
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